Diamond Composites

The Industrial Potential of Diamond-Based Nanomaterials

An introduction to nanodiamond particles: how they are made, what sets them apart from larger diamond grit, and where they are used as additives.

On this page
  1. What nanodiamond is
  2. How it is made
  3. What makes it different
  4. Where it is used as an additive
  5. Practical challenges
  6. A measured outlook

What nanodiamond is

Nanodiamond refers to diamond particles measured in nanometers, where one nanometer is a billionth of a meter. The smallest commonly discussed forms are only a few nanometers across, which means each particle contains a relatively small number of carbon atoms. Diamond nanoparticles are not a different substance from larger diamond; their core is still the diamond lattice. What changes is the proportion of atoms at the surface, which becomes very large at this scale and has an outsized influence on how the particles behave.

Nanodiamond sits alongside other nanoscale carbon forms such as fullerene molecules and carbon nanotubes, and a good place to see how they relate is the broader family of carbon allotropes. Unlike those, though, nanodiamond particles keep the tetrahedral bonding of diamond, at least inside the core.

How it is made

There are several routes. The best known is detonation synthesis, in which an explosive charge containing carbon is detonated in a closed chamber. The shock and heat briefly create conditions in which tiny diamond crystals form. The product is a soot-like mixture that must then be purified to remove non-diamond carbon and metal impurities, usually by chemical treatment. Another route is to grind larger synthetic diamond crystals into very fine powder. A third approach grows diamond from gas phase conditions or uses high pressure on carbon precursors, producing small crystals under controlled settings. Each route yields particles with different size spreads, surface states and impurity levels, which later affects how they can be used.

What makes it different

Surface dominance. Many atoms sit on or near the surface, where bonds are terminated by oxygen-containing groups, hydrogen or other species. The surface chemistry can be modified, which helps in mixing nanodiamond into liquids or polymers.

Clustering. Nanodiamond particles tend to stick together into aggregates, and pulling these apart is one of the hardest practical problems. Even after treatment, a sample often contains clusters of different sizes, not just isolated particles.

Hardness in a small package. Each particle is still made of a very hard material, and as additives they can give a gentle polishing or wear-reducing effect without the scratching associated with coarse grit.

Optical and biological behavior. Certain defects inside a nanodiamond can emit light, a feature linked to nitrogen-vacancy centers, and the particles are being studied for their interaction with biological systems. That research is covered separately and is much less settled than the industrial uses.

Where it is used as an additive

Because nanodiamond is mainly added in small amounts to something else, most of its industrial roles are as an additive.

  • Polishing and finishing. Suspensions of fine diamond particles are used to produce very smooth surfaces on hard materials, where coarser abrasives would leave scratches. Ordinary polishing often uses larger diamond than nanodiamond, so this is one use among several rather than the only choice.
  • Lubricants and greases. Nanodiamond is explored as an additive that may reduce friction and wear under certain conditions. Results vary with the base oil, the dispersion and the operating conditions.
  • Polymers and resins. Small loadings can change stiffness, wear behavior or thermal properties of a polymer. The benefit depends on how well the particles are dispersed and bonded to the polymer.
  • Electroplating and coatings. Adding nanodiamond to a plating bath can produce a metal layer with dispersed hard particles, which may improve wear resistance. The idea is related to composite coatings, although it differs from the continuous layers described under diamond coatings.
  • Seeding for diamond growth. Nanodiamond particles are commonly spread on a surface to act as nucleation sites when a diamond film is grown by chemical vapor deposition. This is a quiet but important use.

Practical challenges

Dispersion is the largest. A nanodiamond additive is only as good as its distribution, and aggregation can cancel any benefit. Purity and consistency come next; different batches may behave differently because of residual carbon or metals. Cost is another factor, since the purification steps are not trivial. Finally, safety and handling deserve attention. Any very fine powder needs careful handling, and the health effects of nanoparticles are an active area of study, so users should rely on current safety information for the specific product.

A measured outlook

Nanodiamond has a clear place as a niche additive, particularly in polishing and in seeding. Wider claims, such as large performance gains in lubricants or structural materials, depend on particular formulations and are not guaranteed. As with other advanced materials, the practical result comes from the combination of particle, carrier and processing rather than from the particle alone.

The complete guide to diamond composites

Diamond-Based Materials for Industrial Applications: A Review
Read the guide

Keep exploring

Guides from other topics

All topics →